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The preparation, characterization, and catalytic performance of porous fibrous LaFeO

Zhifei Wu, Li Wang, Yixiao Hu, Hui Han, Xing Li, Ying Wang

《化学科学与工程前沿（英文）》 2020年 第14卷 第6期   页码 967-975 doi: 10.1007/s11705-020-1922-0

摘要： LaFeO perovskite with a porous fibrous structure was successfully synthesized using a sunflower seed shell as a template. To investigate the effects of this template, a sample was prepared without a template via the same procedure. Through various characterization techniques, such as X-ray diffraction, scanning electron microscopy, Fourier transform infrared spectroscopy, N adsorption-desorption analysis, X-ray photoelectron spectroscopy, oxygen temperature programed desorption, and hydrogen temperature programed reduction, the physiochemical properties of the samples were investigated. The results showed that the sample made with a template had a larger surface area and a larger amount of adsorbed oxygen, which further illustrated that the sunflower seed shell template had a significant impact on the physiochemical properties of the samples. Furthermore, we explored the catalytic activity for nitric oxide (NO) oxidation, and studied the factors affecting it, which highlighted its potential application in automobile exhausts.

关键词： NO oxidation     porous fibrous LaFeO3     sunflower seed shell    

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纤维膜在机械压力下由不透明到透明的转变 Article

王超, 赵景, 刘柳, 张鹏, 王先锋, 俞建勇, 丁彬

《工程（英文）》 2022年 第19卷 第12期   页码 84-92 doi: 10.1016/j.eng.2021.02.018

摘要：

智能可穿戴设备、电子皮肤、空气过滤和组织工程等领域，对透明薄膜材料或基材的需求很大。传统透明材料，如玻璃、塑料等，由于缺乏相互连通的孔道、不理想的孔隙率和柔性，不能满足这些新兴领域的要求。静电纺丝纤维膜因其具有小孔径、高孔隙率和良好的柔性等优点可以弥补传统材料的不足，因此，开发透明的静电纺丝纤维膜具有重大的价值。本文报道了一种简单有效的方法，在不使用任何其他添加剂的情况下，通过机械压力，直接将静电纺丝纤维膜制备成柔性的、有孔的透明纤维膜材料。同时，首次总结了压制后聚合物的透明度性能与分子结构之间的关系。经过机械压力处理后，纤维膜仍可以保持纤维形态、微米级孔道和一定的孔隙率。以聚苯乙烯静电纺丝纤维膜为例，所制备的透明聚苯乙烯纤维膜具有优异的光学性能和机械性能。透明纤维膜可实现高透光率（≈89%，可见光波长在550 nm处）、大孔隙率（10%~30%）和强的机械拉伸强度（≈148 MPa），该拉伸强度约为初始静电纺丝纤维膜的78倍。此外，本文基于透明纤维膜，利用真空辅助抽滤银纳米线和机械压力作用，制备出透明的导电纤维膜材料。与氧化铟锡导电薄膜相比，我们所制备的透明导电纤维膜展示出良好的导电性（9 Ω·sq-1，78%的透光率）和优异的机械性能（可承受大量的弯曲应力）。

关键词： 透明     静电纺丝纤维膜     孔道结构     机械压力     导电    

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Fibrous dysplasia involving the calvarium in children?

Chunquan CAI, Qian LI, Qingjiang ZHANG, Changhong SHEN

《医学前沿（英文）》 2009年 第3卷 第2期   页码 211-215 doi: 10.1007/s11684-009-0024-7

摘要： To gain a broader appreciation of the clinical presentation, operative treatment, and outcome of fibrous dysplasia involving the calvarium in children, we retrospectively reviewed a series of cases of fibrous dysplasia involving the calvarium (4 males and 2 females) with patients’ age ranging from 5 to 12 years old. The clinical manifestation, radiographic findings, surgical treatment, outcome and follow-up were evaluated on the basis of medical records. Fibrous dysplasia in the series was monostotic, involving frontal bone (2 cases), temporal bone (1 case), parietal bone (2 cases) and occipital bone (1 case). The patients most commonly presented with enlarging mass and cosmetic complaints. The treatment given, depending on clinical presentation, was simple biopsy with conservative follow-up (2 cases) to cranial resection (4 cases). All the cases were histopathologically confirmed as fibrous dysplasia. It was demonstrated thatfibrous dysplasia involving the calvarium is a typically benign but slowly progressive disorder of bone. Modern imaging modalities and histopathologic analysis have made diagnosis relatively straightforward. Surgery should be reserved for patients with functional impairment or cosmetic deformity. Because of the benign nature of the condition, the surgery itself should be contemplated with great caution in children.

关键词： fibrous dysplasia     calvarium     monostotic     child    

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Fabrication of three-dimensional porous La-doped SrTiO3 microspheres with enhanced visible light catalytic

Dong Yang, Xiaoyan Zou, Yuanyuan Sun, Zhenwei Tong, Zhongyi Jiang

《化学科学与工程前沿（英文）》 2018年 第12卷 第3期   页码 440-449 doi: 10.1007/s11705-018-1700-4

摘要：

In recent years, much effort has been focused on the development of the photocatalysts with high performance under visible light irradiation. In this paper, three-dimensional porous La-doped SrTiO3 (LST) microspheres were prepared by a modified sol–gel method, in which the agarose gel/SrCO3 microsphere and La2O3 were employed as the template and the La resource, respectively. The as-prepared LST microspheres exhibit a porous structure with a diameter of about 10 µm and a surface pore size of about 100 nm. The La element was doped into the crystal lattice of SrTiO3 by the substitution of La3+ for Sr2+. Therefore, the absorption edge of LST samples shifts toward the visible light region, and their photocatalytic activity for the Cr(VI) reduction is enhanced under visible light. Among all LST samples, LST-0.5 (the La3+ doping content is 0.5 wt-%) exhibited the highest visible-light photocatalytic activity, which can reduce 84% Cr(VI) within 100 min. This LST materials may become a promising photocatalyst for the facile treatment of wastewater containing poisonous heavy metal ions.

关键词： SrTiO3     La3+ doping     porous microsphere     visible-light photocatalysis     Cr(VI) reduction    

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Microwave-assisted catalyst-free hydrolysis of fibrous cellulose for deriving sugars and biochemicals

Songshan Jiang, Helen Daly, Huan Xiang, Ying Yan, Huiping Zhang, Christopher Hardacre, Xiaolei Fan

《化学科学与工程前沿（英文）》 2019年 第13卷 第4期   页码 718-726 doi: 10.1007/s11705-019-1804-5

摘要： Microwave (MW) assisted catalyst-free hydrolysis of fibrous cellulose (FC, cellulolysis) at 200°C promoted a cellulose conversion of ca 37.2% and quantitative production of valuable C5/C6 sugars (e.g , glucose) and the according platform biochemicals (e.g , 5-hydroxymethylfurfural), corresponding to an overall selectivity of 96.5%. Conversely, conventional hydrothermal cellulolysis under similar conditions was not effective, even after 24 h, carbonising the FC. Based on the systematic study of MW-assisted cellulolysis, the specific interaction between water molecules and macroscopic FC under the MW irradiation was proposed, accounting for the interpretation of the experimental observation. The kinetic energy of water molecules under the MW irradiation facilitated the C C (in the non-hindered surface CH OH groups) and C O C bond breaking (inside the cellulose cavities) in FC, producing primary cellulolysis products of xylose, glucose and cellobiose.

关键词： microwave     fibrous cellulose     hydrolysis     sugars     mechanism    

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A 3D porous WP2 nanosheets@carbon cloth flexible electrode for efficient electrocatalytic hydrogen evolution

Mingyu Pi, Xiaodeng Wang, Dingke Zhang, Shuxia Wang, Shijian Chen

《化学科学与工程前沿（英文）》 2018年 第12卷 第3期   页码 425-432 doi: 10.1007/s11705-018-1726-7

摘要：

Self-standing porous WP2 nanosheet arrays on carbon fiber cloth (WP2 NSs/CC) were synthesized and used as a 3D flexible hydrogen evolution electrode. Because of its 3D porous nanoarray structure, the WP2 NSs/CC exhibits a remarkable catalytic activity and a high stability. By using the experimental measurements and first-principle calculations, the underlying reasons for the excellent catalytic activity were further explored. Our work makes the present WP2 NSs as a promising electrocatalyst for hydrogen evolution and provides a way to design and fabricate efficient hydrogen evolution electrodes through 3D porous nano-arrays architecture.

关键词： WP2     nanosheet arrays     hydrogen evolution electrocatalyst     flexible electrode    

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Paratesticular fibrous pseudotumor: a report of five cases and literature review

null

《医学前沿（英文）》 2014年 第8卷 第4期   页码 484-488 doi: 10.1007/s11684-014-0325-3

摘要：

Paratesticular fibrous pseudotumor is a rare benign tumor that originates from intrascrotal tissue, such as tunica vaginalis, epididymis, or spermatic cord. Five cases of fibrous pseudotumor in our hospital were reviewed retrospectively, and the clinical manifestations were analyzed. Three cases of unilateral nodules, comprising one case located in the tunica vaginalis and two cases located in the epididymis, underwent local excision of the unilateral nodule. Two cases of diffuse incrassation in the tunica vaginalis underwent right radical orchiectomy. Postoperative pathological examination showed that all were fibrous pseudotumors. An average follow-up of 26 months showed uneventful results without recurrence for all patients. Fibrous pseudotumor is not a neoplasm but a reactive fibrous inflammatory hyperplasia. Definitive diagnosis requires pathological examination. Radical orchiectomy should be avoided when possible, and local excision should be performed because of the lack of obvious evidence of potential malignancy.

关键词： fibroma     inflammation     scrotum     testicular neoplasm    

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A novel finite element formulation for static bending analysis of functionally graded porous sandwich

Van Chinh NGUYEN; Trung Thanh TRAN; Trung NGUYEN-THOI; Quoc-Hoa PHAM

《结构与土木工程前沿（英文）》 2022年 第16卷 第12期   页码 1599-1620 doi: 10.1007/s11709-022-0891-4

摘要： This article aims to propose a finite element formulation based on Quasi-3D theory for the static bending analysis of functionally graded porous (FGP) sandwich plates. The FGP sandwich plates consist of three layers including the bottom skin of homogeneous metal, the top skin of fully ceramic and the FGP core layer with uneven porosity distribution. A quadrilateral (Q4) element with nine degrees of freedom (DOFs) per node is derived and employed in analyzing the static bending response of the plate under uniform and/or sinusoidally distributed loads. The accuracy of the present finite element formulation is verified by comparing the obtained numerical results with the published results in the literature. Then, some numerical examples are performed to examine the effects of the parameters including power-law index k and porosity coefficient ξ on the static bending response of rectangular FGP sandwich plates. In addition, a problem with a complicated L-shape model is conducted to illustrate the superiority of the proposed finite element method.

关键词： sandwich plates     functionally graded porous     static bending     Quasi-3D theory     Q4 element    

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Predicting the strength properties of slurry infiltrated fibrous concrete using artificial neural network

T. Chandra Sekhara REDDY

《结构与土木工程前沿（英文）》 2018年 第12卷 第4期   页码 490-503 doi: 10.1007/s11709-017-0445-3

摘要： This paper is aimed at adapting Artificial Neural Networks (ANN) to predict the strength properties of SIFCON containing different minerals admixture. The investigations were done on 84 SIFCON mixes, and specimens were cast and tested after 28 days curing. The obtained experimental data are trained using ANN which consists of 4 input parameters like Percentage of fiber (PF), Aspect Ratio (AR), Type of admixture (TA) and Percentage of admixture (PA). The corresponding output parameters are compressive strength, tensile strength and flexural strength. The predicted values obtained using ANN show a good correlation between the experimental data. The performance of the 4-14-3 architecture was better than other architectures. It is concluded that ANN is a highly powerful tool suitable for assessing the strength characteristics of SIFCON.

关键词： artificial neural networks     root mean square error     SIFCON     silica fume     metakaolin     steel fiber    

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Preparation and catalytic performance of La0.8Sr0.2CoO3 supported on the mullite fiber ceramic

ZENG Lingke, LIU Yanchun, LIU Ping′an, WANG Hui, SHUI Anze, DUAN Bilin

《化学科学与工程前沿（英文）》 2007年 第1卷 第4期   页码 372-376 doi: 10.1007/s11705-007-0067-8

摘要： The perovskite-type LaSrCoO supported on the mullite fiber porous ceramics was prepared by means of the impregnating method, and was then characterized by scanning electron microscopy (SEM) and X-ray diffraction (XRD); thus we can come to the conclusion that the perovskite-type composite oxidant can disperse on the surface of mullite fiber ceramics. The catalytic activity of the LaSrCoO for NO and CO was evaluated. The effect of the doped 0.1 wt-% PdCl on the catalytic activity of the perovskite-type LaSrCoO was also discussed. The results show that the conversion rates of NO and CO respectively reaches 74.5% and 99% at 601°C without doped Pd, and both reach 100% at 350°C with a little doped Pd.

关键词： porous     conversion     catalytic activity     electron microscopy     perovskite-type LaSrCoO    

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Fabricating sustainable lignin-derived porous carbon as electrode for high-performance supercapacitors

《化学科学与工程前沿（英文）》 2023年 第17卷 第8期   页码 1065-1074 doi: 10.1007/s11705-023-2313-0

摘要： Lignocellulosic biomass such as plants and agricultural waste are ideal to tackle the current energy crisis and energy-related environmental issues. Carbon-rich lignin is abundant in lignocellulosic biomass, whose high-value transformation and utilization has been the most urgent problem to be solved. Herein, we propose a method for the preparation of porous carbon from lignin employing an H3PO4-assisted hydrothermal method. We characterize the as-prepared lignin-derived porous carbon and investigate its potential for energy storage. After assisted hydrothermal treatment followed by carbonization at 800 °C, the lignin-derived porous carbon displays a high specific capacitance (223.6 F·g–1 at 0.1 A·g–1) and excellent cycling ability with good capacitance retention. In this present study, the resultant lignin-derived porous carbon was used as the electrode of a supercapacitor, illustrating yet another potential high-value use for lignin, namely as a candidate for the sustainable fabrication of main supercapacitor components.

关键词： lignin     porous carbon     electrode     supercapacitor    

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Optimized porous clay heterostructure for removal of acetaldehyde and toluene from indoor air

Pu ZHAO,Lizhong ZHU

《环境科学与工程前沿（英文）》 2016年 第10卷 第2期   页码 219-228 doi: 10.1007/s11783-014-0760-z

摘要： Adsorption is the most widely used technology for the removal of indoor volatile organic compounds (VOCs). However, existing adsorbent-based technologies are inadequate to meet the regulatory requirement, due to their limited adsorption capacity and efficiency, especially under high relative humidity (RH) conditions. In this study, a series of new porous clay heterostructure (PCH) adsorbents with various ratios of micropores to mesopores were synthesized, characterized and tested for the adsorption of acetaldehyde and toluene. Two of them, PCH25 and PCH50, exhibited markedly improved adsorption capability, especially for hydrophilic acetaldehyde. The improved adsorption was attributed to their large micropore areas and high micropore-to-mesopore volume ratios. The amount of acetaldehyde adsorbed onto PCH25 at equilibrium reached 62.7 mg·g , eight times as much as the amount adsorbed onto conventional activated carbon (AC). Even at a high RH of 80%, PCH25 removed seven and four times more of the acetaldehyde than AC and the unmodified raw PCHs did, respectively. This new PCH optimized for their high adsorption and resistance to humidity has promising applications as a cost-effective adsorbent for indoor air purification.

关键词： porous clay heterostructure     volatile organic compounds     adsorption     adsorbent     indoor air    

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Maximum entropy based finite element analysis of porous media

Emad NOROUZI, Hesam MOSLEMZADEH, Soheil MOHAMMADI

《结构与土木工程前沿（英文）》 2019年 第13卷 第2期   页码 364-379 doi: 10.1007/s11709-018-0470-x

摘要： The maximum entropy theory has been used in a wide variety of physical, mathematical and engineering applications in the past few years. However, its application in numerical methods, especially in developing new shape functions, has attracted much interest in recent years. These shape functions possess the potential for performing better than the conventional basis functions in problems with randomly generated coarse meshes. In this paper, the maximum entropy theory is adopted to spatially discretize the deformation variable of the governing coupled equations of porous media. This is in line with the well-known fact that higher-order shape functions can provide more stable solutions in porous problems. Some of the benchmark problems in deformable porous media are solved with the developed approach and the results are compared with available references.

关键词： maximum entropy FEM     fully coupled multi-phase system     porous media    

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S-enriched porous polymer derived N-doped porous carbons for electrochemical energy storage and conversion

Chao Zhang, Chenbao Lu, Shuai Bi, Yang Hou, Fan Zhang, Ming Cai, Yafei He, Silvia Paasch, Xinliang Feng, Eike Brunner, Xiaodong Zhuang

《化学科学与工程前沿（英文）》 2018年 第12卷 第3期   页码 346-357 doi: 10.1007/s11705-018-1727-6

摘要：

Porous polymers have been recently recognized as one of the most important precursors for fabrication of heteroatom-doped porous carbons due to the intrinsic porous structure, easy available heteroatom-containing monomers and versatile polymerization methods. However, the heteroatom elements in as-produced porous carbons are quite relied on monomers. So far, the manipulating of heteroatom in porous polymer derived porous carbons are still very rare and challenge. In this work, a sulfur-enriched porous polymer, which was prepared from a diacetylene-linked porous polymer, was used as precursor to prepare S-doped and/or N-doped porous carbons under nitrogen and/or ammonia atmospheres. Remarkably, S content can sharply decrease from 36.3% to 0.05% after ammonia treatment. The N content and specific surface area of as-fabricated porous carbons can reach up to 1.32% and 1508 m2·g−1, respectively. As the electrode materials for electrical double-layer capacitors, as-fabricated porous carbons exhibit high specific capacitance of up to 431.6 F·g−1 at 5 mV·s−1 and excellent cycling stability of 99.74% capacitance retention after 3000 cycles at 100 mV·s−1. Furthermore, as the electrochemical catalysts for oxygen reduction reaction, as-fabricated porous carbons presented ultralow half-wave-potential of 0.78 V versus RHE. This work not only offers a new strategy for manipulating S and N doping features for the porous carbons derived from S-containing porous polymers, but also paves the way for the structure-performance interrelationship study of heteroatoms co-doped porous carbon for energy applications.

关键词： porous polymers     porous carbons     sulfur and nitrogen doping     supercapacitor    

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Hierarchically porous materials: Synthesis strategies and emerging applications

Minghui Sun, Chen Chen, Lihua Chen, Baolian Su

《化学科学与工程前沿（英文）》 2016年 第10卷 第3期   页码 301-347 doi: 10.1007/s11705-016-1578-y

摘要： Great interests have arisen over the last decade in the development of hierarchically porous materials. The hierarchical structure enables materials to have maximum structural functions owing to enhanced accessibility and mass transport properties, leading to improved performances in various applications. Hierarchical porous materials are in high demand for applications in catalysis, adsorption, separation, energy and biochemistry. In the present review, recent advances in synthesis routes to hierarchically porous materials are reviewed together with their catalytic contributions.

关键词： hierarchically porous materials     synthesis     application    

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标题 作者 时间 类型 操作

The preparation, characterization, and catalytic performance of porous fibrous LaFeO

Zhifei Wu, Li Wang, Yixiao Hu, Hui Han, Xing Li, Ying Wang

期刊论文

纤维膜在机械压力下由不透明到透明的转变

王超, 赵景, 刘柳, 张鹏, 王先锋, 俞建勇, 丁彬

期刊论文

Fibrous dysplasia involving the calvarium in children?

Chunquan CAI, Qian LI, Qingjiang ZHANG, Changhong SHEN

期刊论文

Fabrication of three-dimensional porous La-doped SrTiO3 microspheres with enhanced visible light catalytic

Dong Yang, Xiaoyan Zou, Yuanyuan Sun, Zhenwei Tong, Zhongyi Jiang

期刊论文

Microwave-assisted catalyst-free hydrolysis of fibrous cellulose for deriving sugars and biochemicals

Songshan Jiang, Helen Daly, Huan Xiang, Ying Yan, Huiping Zhang, Christopher Hardacre, Xiaolei Fan

期刊论文

A 3D porous WP2 nanosheets@carbon cloth flexible electrode for efficient electrocatalytic hydrogen evolution

Mingyu Pi, Xiaodeng Wang, Dingke Zhang, Shuxia Wang, Shijian Chen

期刊论文

Paratesticular fibrous pseudotumor: a report of five cases and literature review

null

期刊论文

A novel finite element formulation for static bending analysis of functionally graded porous sandwich

Van Chinh NGUYEN; Trung Thanh TRAN; Trung NGUYEN-THOI; Quoc-Hoa PHAM

期刊论文

Predicting the strength properties of slurry infiltrated fibrous concrete using artificial neural network

T. Chandra Sekhara REDDY

期刊论文

Preparation and catalytic performance of La0.8Sr0.2CoO3 supported on the mullite fiber ceramic

ZENG Lingke, LIU Yanchun, LIU Ping′an, WANG Hui, SHUI Anze, DUAN Bilin

期刊论文

Fabricating sustainable lignin-derived porous carbon as electrode for high-performance supercapacitors

期刊论文

Optimized porous clay heterostructure for removal of acetaldehyde and toluene from indoor air

Pu ZHAO,Lizhong ZHU

期刊论文

Maximum entropy based finite element analysis of porous media

Emad NOROUZI, Hesam MOSLEMZADEH, Soheil MOHAMMADI

期刊论文

S-enriched porous polymer derived N-doped porous carbons for electrochemical energy storage and conversion

Chao Zhang, Chenbao Lu, Shuai Bi, Yang Hou, Fan Zhang, Ming Cai, Yafei He, Silvia Paasch, Xinliang Feng, Eike Brunner, Xiaodong Zhuang

期刊论文

Hierarchically porous materials: Synthesis strategies and emerging applications

Minghui Sun, Chen Chen, Lihua Chen, Baolian Su

期刊论文